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Formation of calcium silicide on three types of templates: Si(111)7 × 7, 2D Mg2Si, and 3D Mg2Si, was studied during Ca deposition at 120 °C in situ by Auger and electron energy loss spectroscopy, and by differential optical reflectance spectroscopy. A continuous Ca2Si layer is formed on 2D and 3D Mg2Si templates; but, on an atomically clean silicon surface (Si(111)7 × 7), a mixture of Ca2Si with another...
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