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Two bowlic cyclotriveratrylene CTV-1 and CTV-2, with different peripheral groups of —OCH3 and —OCH2CH3 for CTV-1 and —OCH3 and —OCH2COOCH3 for CTV-2, respectively, were synthesized by typical trimerization via a multistep sequence from vanillin. Both bowlic CTV molecules were thermotropic liquid crystals, and presented typical grainy textures of the nematic phase and homogeneous texture of the single...
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