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Artificial photosynthesis is a promising strategy for converting carbon dioxide (CO2) and water (H2O) into fuels and value‐added chemical products. However, photocatalysts usually suffered from low activity and product selectivity due to the sluggish dynamic transfer of photoexcited charge carriers. Herein, we describe anchoring of Ag single atoms on hollow porous polygonal C3N4 nanotubes (PCN) to...