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Thermodynamics and annealing behavior of swift heavy ion amorphized Dy2Sn2O7 pyrochlore were studied. Its amorphization enthalpy, defined as the total energetic difference between the irradiation amorphized and undamaged Dy2Sn2O7 states, was determined to be 283.6 ± 6.5 kJ/mol by high temperature oxide melt drop solution calorimetry. It has been an enigma that stannate and some other pyrochlores do...
Utilizing a combined approach of high temperature calorimetry and neutron total scattering, we obtained critical insights into the energetics and annealing of radiation damage in swift heavy ion irradiated Dy2Ti2O7 pyrochlore. Oxide melt solution calorimetry reveals that the radiation amorphized Dy2Ti2O7 is destabilized by 243 kJ/mol compared to fully ordered, crystalline pyrochlore. Differential...
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