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A novel series of Zr 1−x Zn x P 2 O 7 (x=0.00, 0.03, 0.06, 0.1) was prepared by a solid state reaction method. XRD patterns indicated that all the samples exhibited a single cubic phase structure except Zr 0.9 Zn 0.1 P 2 O 7 . The conduction behavior was investigated using various electrochemical methods including ac impedance spectroscopy,...
Tin pyrophosphate, SnP 2 O 7 , is prepared with various initial molar ratios of phosphorus vs. metal ions, P ini /Sn, and different heat-treating temperatures from 573 to 923K. The preparation conditions are optimized giving consideration to the influence of H 3 PO 4 concentration, P ini /Sn molar ratio and heat-treating temperature. The ionic conduction...
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