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The isothermal crystallization of isomorphic Poly(hexamethylene adipate-co-butylene adipate) [P(HA-co-BA)], with the HA unit content ranged from 100 to 45 mol%, forming the Poly(hexamethylene adipate) [PHA] type crystal was investigated with DSC, FTIR and WAXD. The BA units were found adopting their all-trans conformation in the crystalline phase of PHA type crystal. The inclusion of the BA units...
The enzymatic hydrolysis behavior of compositionally well-fractionated bacterial poly(3-hydroxybutyrate-co-3-hydroxyvalerate) [P(3HB-co-3HV)] with 3HV-unit content from 8 to 98 mol% and bacterial poly(3-hydroxybutyrate) [P(3HB)] has been investigated in the presence of poly(3-hydroxyalkanoate) depolymerases isolated from Ralstonia pickettii T1 and Acidovorax sp. TP4. The water-soluble degradation...
Two different kinds of natural poly(3-hydroxybutyric acid-co-3-hydroxypropionic acid)s [P(3HB-co-3HP)] with individual 3HP comonomer contents of 36.5 and 68.1 mol.% were biosynthesized by the bacteria Alcaligenes latus, fed on the cosubstrates of (R)-3-hydroxybutyric acid (3HBA) and 3-hydroxypropionic acid (3HPA). Employing the mixed chloroform/n-heptane solvent, the bacterial products were found...
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