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Synchrotron Far-IR RAIRS data for atomic O and a range of complex oxygen-containing molecular species on Cu(110) and Cu(100) surfaces are presented. For the latter group of adsorbates, it can be seen that instrument upgrades have enabled the monitoring of low intensity bands with high resolution. Atomic oxygen adsorbed in the long-bridge position in the (2x1) reconstructed phase on Cu(110) gives rise...
The adsorption and reaction of propan-2-ol on Ni(111) has been followed by reflection absorption IR spectroscopy and temperature programmed desorption. At 110 K, nondissociative molecular adsorption is observed in the monolayer, with randomly oriented multilayers observed at higher exposures. On increasing substrate temperature to 200 K, scission of the OH bond is observed with formation of a 2-propoxide...
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