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The reactions of the rhenium(V) dihalides TpRe(O)Cl 2 , Cp * Re(O)Cl 2 and Cp * Re(N t Bu)Cl 2 with the dilithium derivative of 1,1 -ferrocene dithiol and diselenol, respectively, have been used to prepare heterodimetallic complexes which contain both rhenium (in the center of a half-sandwich complex) and iron (in the sandwich cage). The six new complexes...
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