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Poly(ethylene oxide) star polymers (PEO stars) were prepared by atom transfer radical polymerization of 2000 molecular weight PEO methacrylate macromonomer with divinylbenzene as a crosslinking co-monomer. With an average of 460arms per star, these PEO stars had a 12nm radius of gyration that is consistent with a dense polymer core surrounded by an extended PEO corona. The PEO stars were extremely...
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