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Chemical speciation and concentrations of reactive gaseous mercury (RGM) in the urban atmospheric boundary layer (ABL) have been modeled using a photochemical box model. Measurements for gaseous elemental mercury (GEM) and the relevant trace gases were carried out in Seoul (37.6°N, 127°E), Korea, during a one-year period from March 2001 to February 2002. A moderately strong inverse correlation between...
This study reports the impact of reactive halogen species on diurnal ozone changes in the marine boundary layer (MBL). A photochemical box model has been used to simulate the mixing ratios of ozone, constrained with airborne field observations of Lagrangian flights operated during the ACE 1 campaign, 1995. The model includes bromine, chlorine, and iodine chemistry as well as aqueous-phase chemistry...
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