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Die Eintopfsynthese eines Nylon‐6‐Monomers durch Kombination zweier redoxneutraler biokatalytischer Module (grauer Kasten und Reaktionskolben) ist Thema der Zuschrift von W. Kroutil et al. auf S. 14377 ff. Die Kaskade ist als elektrischer Schaltkreis dargestellt, wobei jedes Enzym an einer Kreuzung gezeigt ist und eine In‐situ‐Maskierung die unerwünschte Inhibierung durch ein Intermediat verhindert...
The combination of two cofactor self‐sufficient biocatalytic cascade modules allowed the successful transformation of cyclohexanol into the nylon‐6 monomer 6‐aminohexanoic acid at the expense of only oxygen and ammonia. A hitherto unprecedented carboxylic acid capping strategy was introduced to minimize the formation of the dead‐end intermediate 6‐hydroxyhexanoic acid. For this purpose, the precursor...
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