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ZnS thin films were deposited on glass and polymer substrates using a reaction between thiourea and a stable zinc complex, Zn(en)3SO4 (en: ethylenediamine) or Zn(trien)(ClO4)2 (trien: triethylenetetraamine), in alkaline media. In a weak alkaline solution, Zn(OH)2 films were formed. The deposition reactions were controlled by the supply of sulfide ions from thiourea at a suitable rate in alkaline media...
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