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The poisoning effect of carbon disulfide on cubooctahedral palladium nanoparticles (1.5, 3.0 or 4.6 nm in mean diameter) deposited on montmorillonite was investigated in the liquid-phase hydrogenation of styrene to ethylbenzene under mild conditions. The dispersion of the metal crystallites was computed as a function of the mean diameter in terms of face atoms, of edge atoms + corner atoms, and of...
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