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PCBM is a fullerene derivative (phenyl‐C61‐butyric acid methyl ester) considered to be one of the best n‐type organic semiconductors and plays a relevant role in organic photovoltaic solar cells. Much effort has been devoted to the optimization of the synthesis of PCBM derivatives. In this paper, PC61BM and PC71BM fullerene mono‐adducts but also PCBM‐like derivatives are successfully prepared by a...
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