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Although various excellent electrocatalysts/adsorbents have made notable progress as sulfur cathode hosts on the lithium‐sulfur (Li‐S) coin‐cell level, high energy density (WG) of the practical Li‐S pouch cells is still limited by inefficient Li‐ion transport in the thick sulfur cathode under low electrolyte/sulfur (E/S) and negative/positive (N/P) ratios, which aggravates the shuttle effect and sluggish...