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The quinolyl-functionalised Cp-chromium(III) complexes 1 and 2, which serve as precursors for highly active olefin polymerisation catalysts, were alkylated with benzylmagnesium chloride. From these reactions, the new metal complexes 4, 5 and 6 were obtained and structurally characterised. The expected alkylchromium compound 4 is formed together with complex 5, where the nucleophile replaced a hydrogen...
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