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The digallium compound R2GaGaR2 (1; R=CH(SiMe3)2) reacts with citracinic acid by the release of two equivalents of bis(trimethylsilyl)methane and the formation of a unique oligofunctional cage compound (2). Four GaGa bonds in a tetrahedral arrangement are bridged by four spacer ligands that are located on the faces of the tetrahedron and bridge the gallium atoms of three different GaGa bonds. Four...
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