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Borverbindungen In ihrer Zuschrift auf S. 15436 berichten Y. Yamamoto et al. über die Isolierung einer gebogenen Bor‐Kette, in der drei Boratome über Mehrfachbindungen ohne zusätzliche Liganden verknüpft sind. Diese Spezies kann auch als ein Bis(borylen)‐stabilisiertes Borylen aufgefasst werden.
A triaminotriborane(3) was isolated as purple crystals through the reduction of (TMP)BCl2 (TMP=2,2,6,6‐tetramethylpiperidino) by sodium naphthalenide. Single‐crystal X‐ray diffraction and computational studies of the obtained triaminotriborane(3) revealed a bent structure of the [B(NR2)]3 chain. The bond lengths between the central and terminal boron atoms were similar to those observed in neutral...
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