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Iron(II), (Fe(H2O)62+, (FeII) participates in many reactions of natural and biological importance. It is critically important to understand the rates and the mechanism of FeII oxidation by dissolved molecular oxygen, O2, under environmental conditions containing bicarbonate (HCO3−), which exists up to millimolar concentrations. In the absence and presence of HCO3−, the formation of reactive oxygen...
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