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Catalytically active molybdenum oxycarbide has been successfully prepared on an efficient carrier, SiC. Comparisons with the conventional alumina support show that the strong interaction between MoO 3 , the starting material, and Al 2 O 3 , partially blocks the formation of the oxycarbide; the active phase can only be prepared at very high loading. X-ray diffraction and temperature-programmed...
Controlled reduction of MoO 3 can produce different phases of catalytic interest. One of these phases has been considered as being an oxycarbide of molybdenum. Various techniques mainly TEM but also XRD and others have been extensively used to understand the mechanism of formation and the structure of this oxycarbide. Its structure is reminiscent of the MoO 3 structure as shown by...
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