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A biomimetic model for protein/lipid radical damage is described. The model shows that the protein degradation is accompanied by trans lipid isomerization due to thiyl radicals, derived from sulfur-containing residues and diffused through the lipid bilayer. γ-Irradiation was used to obtain free radical generation and lysozyme was chosen as enzyme example.A detailed study of the Raman spectra of lysozyme...
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