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Trans-cyclohexane-backbone iridium complexes with different axial chirality were synthesized from (1R,2S)-2-(pyridin-2-yl) cyclohexanol, and their application in asymmetric hydrogenation of (2H-chromen-3-yl)methanols was investigated. When the hydrogenation was carried out using 1% Ir-8 as the catalyst at a hydrogen pressure of 5 MPa in dichloromethane for 16 h at room temperature, excellent activities...
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