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The Electrochemically Stimulated Conformational Relaxation (ESCR) model has been applied to simulate voltammetric responses of polypyrrole films previously submitted to high cathodic potentials for long times. Large anodic oxidation overpotentials (> 200 mV) and fast switching rates, linked to a strong compactation of the polymeric structure by cathodic polarization, are predicted by the model...
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