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Inorganic planar ring‐shape molecules with 4n + 2 π electrons are always the focus of experimental synthesis and theoretical research due to their potential aromaticity and stability. In this work, the whole series of five‐membered heterocycle monoanions XnY5‐n− (X, Y = group 15 elements; n = 1‐4) were thoroughly investigated by means of density functional theory calculations. They all have large...
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