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A gas diffusion electrode system that can supply gaseous substrates to enzymes from the gas phase in bioelectrocatalysis is essential to increase the mass-transfer of gaseous substances; such a system can also address the problem of mass-transfer-limited reactions for gaseous substrates with low solubility in the dissolved system. We have constructed gas diffusion dioxygen (O2)-reducing biocathodes...
Bilirubin oxidase (BOD) catalyzes 4e−-reduction of O2 into H2O and is one of the enzymes allowing direct electron transfer (DET)-type bioelectrocatalysis. Mesoporous carbon materials are often used for constructing BOD-modified DET-type biocathodes. We have examined the performance of several multi-walled carbon nanotubes (MWCNTs) as cathode platforms for BOD-catalyzed bioelectrocatalytic O2 reduction...
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