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The biological buffer 4-(2-hydroxyethyl)piperazine-1-ethanesulfonic acid sodium (HEPES-Na) was found that can induce liquid–liquid phase splitting in the aqueous solutions of 1,3-dioxolane, 1,4-dioxane, acetonitrile, and tert-butanol at ambient conditions. To prepare the phase diagrams, we measured the solid–liquid equilibrium (SLE), solid–liquid–liquid equilibrium (SLLE), and liquid–liquid equilibrium...
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