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The coordination geometry and supramolecular structures of three copper(II) complexes of two α-hydroxycarboxylates and one α-methoxycarboxylate with nitrogen donor co-ligands are discussed. The complexes have been characterized by elemental analysis, ESI-MS, IR and electronic spectroscopy, thermogravimetric analysis and magnetic measurements. The X-ray structure analysis of all the complexes, namely...
Two trinuclear copper(II) complexes of a Schiff-base type N 4 O-donor ligand (LH) derived from 4,4,9,9-tetramethyl-5,8-diazadodecane-2,11-dione and 1,3-diaminopropan-2-ol are reported. Complex [Cu 3 L 2 (ClO 4 ) 4 ] (1) has an angular C 2 -symmetric trinuclear core as revealed from single-crystal X-ray diffraction studies. The terminal coppers are in...
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