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The use of a range of modern analytical techniques has facilitated the structural characterisation of the polysaccharide from the New Zealand endemic red alga, Callophyllis hombroniana. The native polysaccharide contains a number of structural units with the largest proportion consisting of 3-linked β-d-galactopyranosyl 2-sulfate units, alternating with 4-linked 3,6-anhydro-α-d-galactopyranosyl 2-sulfate...
The highly complex polysaccharide extracted from the New Zealand red alga Pachymenia lusoria (Grev.) J. Ag. has been characterised and certain structural features defined. A reductive hydrolysis procedure was used for constituent sugar and linkage analyses, with trideuteriomethylation being employed to enable the location of natural methyl ether groups to be determined. A reductive partial-hydrolysis...
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