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Precipitation in the diffusion zone of Fe-1.62wt.%Mn and Fe-0.56wt.%V alloys nitrided at 843 K was studied by TEM and XRD analyses. Recent thermodynamic data have been used to interpret the different results in both systems. In the manganese containing alloy, the thermodynamically stable θ-Mn 6 N 5 phase precipitates in the diffusion zone. Around the maximum hardness, in a narrow zone...
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