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Two new organically templated copper halides, (nbq)4Cu4I8 (1) and [(ipq)2(Cu5I7)]n (2) have been synthesized in the presence of nbq+ and ibq+ (nbq+ = N-(n-butyl)-quinolinium, ibq+ = N-(iso-pentyl)-quinolinium) acting as structure-directing agents(SDAs). Both of the compounds present hybrid structures with SDAs and inorganic moieties being incorporated. In 1, tetrameric Cu4I84− anion is composed...
A novel 1-D organic–inorganic silver(I)-iodide coordination architecture [(C10H16N)3(Ag6I9)]n (1) (C10H16N+=N-butyl-2-methyl-pyridinium) templated by appropriate cation has been constructed and structurally and optically characterized. The inorganic moiety of 1 presents one-dimensional hackle chain arrangement that results from the edges-sharing of AgI4 tetrahedrons. Static attracting interactions...
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