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Liquid–liquid equilibrium (LLE) data of the solubility curves and tie-line compositions have been determined for mixtures of (water+2,3-butanediol+ethyl acetate) at 298.15, 308.15 and 318.15K and atmospheric pressure. Distribution coefficients and separation factors have been evaluated for the immiscibility region. The reliability of the experimental tie lines has been confirmed by using Othmer–Tobias...
Isobaric vapor–liquid equilibria data have been determined at 101.3kPa for the binary mixtures of (2,3-butanediol+n-butanol), (2,3-butanediol+ethyl acetate) and (2,3-butanediol+butyl acetate). Thermodynamic consistency has been tested for all vapor–liquid equilibria data. The non-ideality of the vapor phase has been considered by using Hayden–O’Connell equation. The activity coefficients have been...
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