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This paper deals with the prediction of adsorption equilibrium and kinetics of hydrocarbons onto activated carbon samples having different micropore size distribution (MPSD). The microporous structure of activated carbon is characterised by the distribution of slit-shaped micropores, which is assumed to be the sole source of surface heterogeneity. The interaction between adsorbate molecule and pore...
This paper addresses the azeotropic behaviour of adsorption occurring on a heterogeneous solid, which is composed of patches of different adsorption energies. One of the adsorbates is excluded from adsorption onto one or more patches. If such species is the weaker adsorbing species, then the azeotropic behaviour does not occur. On the other hand, if that species is the stronger adsorbing species then...
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