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IR, Raman and surface-enhanced Raman scattering (SERS) spectra of pindolol (PIN) and verapamil (VER) were recorded, and the vibrational bands were assigned on the basis of density functional theory (DFT) calculations. The adsorption geometry to the silver surface of the investigated drugs was derived by considering the molecular electrostatic potential (MEP) and the SERS surface selection rules. Both...
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