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X-ray photoelectron diffraction measurements have been made for the Cu(111)(2 2)-Cs and Cu(111)(2 2)-K systems to explore the possibility of using substrate emission XPD for the elucidation of adsorbate-substrate registry in these cases of strongly scattering adsorbate atoms and anticipated atop adsorption sites. Although scattering effects within the substrate, for sub-surface emitters, clearly...