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Suspensions of diblock and triblock copolymer particles comprising a poly(n-butyl acrylate) first/central block and polystyrene or poly(methyl methacrylate) second/outer blocks were synthesized by nitroxide-mediated controlled/living free-radical emulsion polymerization. Monofunctional and difunctional alkoxyamines based on the nitroxide SG1 were used as initiators. For the sake of simplicity, sequential...
This feature article describes the application of nitroxide-mediated controlled/living free-radical polymerization in aqueous dispersed systems such as miniemulsion and emulsion polymerizations. It mainly focuses on the acyclic nitroxide SG1 with derived alkoxyamines and aims to show how the recent development of new water-soluble species has allowed a true emulsion polymerization process to be successfully...
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