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In this study, palladium particles supported on carbon black (Vulcan XC‐72) (Pd/C) and corncob biochar (Pd/CB800, Pd/CB900, and Pd/CB1000) were successfully synthesized using borohydride reduction. The biochar support was obtained from corncob waste via pyrolysis from 800 to 1000°C. Scanning electron microscopy with energy dispersive x‐ray (SEM–EDX) revealed successful deposition of Pd metal particles...