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Ceramic materials from the A2M3O12 family with near‐zero thermal expansion are good candidates for applications requiring high thermal shock resistance. Considering their inherently low thermal conductivity, the bulk forms of A2M3O12 have to present Young's moduli and mechanical strength close to 100 GPa and 100 MPa, respectively, in order to compete with the state‐of‐the‐art materials used to avoid...
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