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We report the gas sorption ability of [Cd(μ-hmt)(μ-dca) 2 ] n (1) (hmt=hexamethylenetetramine, dca=dicyanamide), a coordination polymer with 2D rectangular grid structure known as the porous non-porous materials, for CO 2 , CH 4 , and N 2 under different temperatures (295K, 195K). It was observed that polymer adsorbs CO 2 and CH 4 , but not N...
Acetic anhydride mediates a facile and rapid condensation of benzimidazole with aromatic o-diacid dichlorides to precipitate p-dione adducts in excellent yields. Condensation with pyridine-3,4-dicarbonyl dichloride produced a 1:1 mixture of isomeric p-diones. The X-ray crystal structure of one of the latter isomers revealed unusual high density, and inter-layer separation similar to graphite. Cyclic...
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