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A tetrazole-based Zn(II) coordination polymer, [Zn(tzf) 2 ] n 1 (Htzf=1H-tetrazole-5-formic acid), was synthesized by reaction of ZnCl 2 and Htzf, and structurally characterized by single-crystal X-ray diffraction. Polymer 1 features a 3D-diamond-like net formed by the linkage of Zn(II) atoms and tetrazole groups. The carboxylate O atoms in tzf ligand remain uncoordinated....
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