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The interaction of Nd(III) with four carboxylated pyridine N-oxide derivatives in aqueous solutions is studied by UV–vis absorption spectroscopy. From factor analysis in combination with computer-intensive bootstrap resampling methods the empirical probability distributions of the formation quotients of the 1:1 Nd(III) complexes with nicotinic acid N-oxide (I), picolinic acid N-oxide (II), pyridine...
Threshold bootstrap computer-assisted target factor analysis (TB CAT) has been applied to the evaluation of UV-Vis spectra of Nd(III) in aqueous solutions containing varying amounts of pyridine 2,4-dicarboxylic acid N-oxide (dipyr NO). Using the total uncertainty budget concept, probability distributions of the conditional formation constant(s) of the respective Nd(III) dipyr NO species have been...
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