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This review aims to use the results of an approach combining crystallographic structure analysis with mutational studies as a framework for the various mechanistic proposals advanced in attempts to explain the astonishing acceleration rates displayed by orotidine 5′-monophosphate decarboxylase, the most proficient enzyme known. Special emphasis is placed on the contributions of active site amino acids...
This review aims to use the results of an approach combining crystallographic structure analysis with mutational studies as a framework for the various mechanistic proposals advanced in attempts to explain the astonishing acceleration rates displayed by orotidine 5′-monophosphate decarboxylase, the most proficient enzyme known. Special emphasis is placed on the contributions of active site amino acids...
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