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The Fe–Zn and Fe–Al-based alloying phases are formed on galvanized/galvannealed steels which are extensively used as automobile bodies. This paper investigated the effects of Si on the formation of intermetallic phases in the alloying reaction between an iron substrate and liquid Zn containing 0.2 wt% Al and partitioning of Si between the phases. The addition of Si to the iron substrate was found...
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