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Heterogeneous hydrogenations of 1-naphthol and 2-naphthol over Ru/Al 2 O 3 -9001 (from Engelhard) are presented. It was found that 1-naphthol provides almost exclusively (98–100%) the cis-decalols (OH equatorial and axial) while the 2-naphthol lead to mixtures of a cis-decalol (OH equatorial) and a trans-decalol (OH equatorial) in 1/1–1/2 ratio where the trans-decalol is major. A rapid...
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