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Considering the chalcopyrite/defect-chalcopyrite junction model for Cu(In 1−x Ga x )Se 2 -based devices and our previously reported findings for the Cu(In 1−x Ga x ) 3 Se 5 defect chalcopyrites, we have postulated that uniform high-Ga-content photovoltaic structures (with x > 0.35) do not yield acceptable device performance due to the electrical...
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