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Effective separation of ethyne from ethyne/ethylene (C2H2/C2H4) mixtures is a challenging and crucial industrial process. Herein, an ultra‐microporous metal–organic framework (MOF) platform, Cd(dicarboxylate)2(ditriazole), with triangular channels is proposed for high‐efficiency separation of C2H2 from C2H4. The targeted structures are constructed via a mixed‐ligand strategy by selecting different‐sized...
Functionalized porous aromatic frameworks (PAFs) are excellent candidate materials for hybrid membrane fabrication. However, tailoring PAFs for membrane CO2 separation with desirable performance is still a challenge. Here, facile fabrication of functional hybrid alkylamine‐modified PAF‐1 containing membranes with high compatibility for efficient CO2/N2 separation is reported. The methylamino groups...
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