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The structural features of two new copper(II) nitrato complexes with 3-bromoquinoline, [Cu(3BrQ)2(NO3)2] (1), and 6-methylquinoline, [Cu(6MeQ)2(NO3)2] (2), were investigated using X-ray single crystal structure determination, combined with Hirshfeld topology analysis of the molecular packing. Both complexes consist of two quinoline ligands and two bidentate nitrate ions hexa-coordinating the central...
The reaction of trans-[PtCl2(NCR)2] (R1=CH2CO2Me (1a), R2=CH2Cl (1b)) with pyrroline N-oxide −O+NCHCH2CH2CMe2 (4), at room temperature for 15min, furnishes via [3+2] cycloaddition the fused bicyclic Δ4-1,2,4-oxadiazoline Pt(II) complexes trans-[PtCl2{NC(R)ONC(H)CH2CH2CMe2}2] (R1=CH2CO2Me (5a), R2=CH2Cl (5b)). Compounds 5a and 5b were refluxed in CH2Cl2 for 1week to afford the derived ketoimine Pt(II)...
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