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The adsorption and oxidation behavior of rutin was studied by in-situ UV spectroelectrochemistry in a long optical-path thin-layer electrochemical cell with a graphite-wax electrode. The dynamic UV spectra of rutin under potentiostatic oxidation were recorded, which indicated the formation of o-quinonic structure. During the repetitive cyclic potential scans, cyclic voltabsorptomogram was recorded...
This paper describes a novel method of obtaining cyclic voltammograms (CVs) from optical signals. The obtained CVs correspond to the various specific species involved in the electrode process, which give more detailed information on the system under investigation than the common CV. For this purpose cyclic voltabsorptometry was used to investigate the successive oxidation processes of rutin on a graphite-wax...
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