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The stability of six dioctahedral smectites with different crystal chemistry was studied in the presence of iron to simulate the possible reactions of clay minerals in contact with Fe canister in a nuclear waste repository. The batch experiments were performed at 75°C for 35days in air. The reaction products were examined by XRD, QXRD, FTIR, BWA analyses and UV–Vis spectroscopy. The reaction of bentonites...
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