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A Pd/CuCl2/γ-Al2O3 catalyst of high activity (up to 87%) and of sulfur-poisoning resistance to SO2 as high as 10,000ppm was designed for the selective catalytic oxidation of Hg0 for the first time. It was found that Pd and CuCl2 function as active sites of Hg0 adsorption and HCl activation, respectively. The combination of these two phases could improve the regeneration and migration of active chlorine,...
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