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The generally observed decrease of the electrostatic energy in the complex with increasing solvent polarity has led to the assumption that the stability of the complexes with ion‐pair hydrogen bonds decreases with increasing solvent polarity. Besides, the smaller solvent‐accessible surface area (SASA) of the complex in comparison with the isolated subsystems results in a smaller solvation energy of...
The generally observed decrease of the electrostatic energy in the complex with increasing solvent polarity has led to the assumption that the stability of the complexes with ion‐pair hydrogen bonds decreases with increasing solvent polarity. Besides, the smaller solvent‐accessible surface area (SASA) of the complex in comparison with the isolated subsystems results in a smaller solvation energy of...